BPTSF - U-2502 ISOCYANATE
- MSDS: BPTSF
- Manufacturer: CASTALL INC
- Product Name: U-2502 ISOCYANATE
- National Stock Number: 8040-00N034138
Product Identification
Product ID:U-2502 ISOCYANATE
MSDS Date:03/31/1986
FSC:8040
NIIN:00N034138
MSDS Number: BPTSF
Responsible Party
EAST WEYMOUTH, MA 02189
US
Emergency Phone: 617-337-6075
Info Phone: 617-337-6075
Cage: DO809
Contractor
Telephone: 617-337-6075
Cage: 29966
Ingredients
ELEMENTS MUST BE ENSURED. OBSERVE OSHA REGULATIONS
RTECS: 9999999ZZ
RUBBER, POLYVINYL ALCOHOL).
RTECS: 9999999ZZ
PRDCE REDDEN, SWELL/BLISTER, & IN SOME INDIVIDUALS
RTECS: 9999999ZZ
IRRITATING TO EYES & CAN CAUSE LACHYRMATION (TEARING
RTECS: 9999999ZZ
ARE THAT THE DMG IS REVERSIBLE & DOES NOT RSLT IN
RTECS: 9999999ZZ
ACTION IN MOUTH, STOM TISSUE & DIGEST TRACT. HOWEVER,
RTECS: 9999999ZZ
DO NOT
RTECS: 9999999ZZ
DO NOT GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
RTECS: 9999999ZZ
CNDTNS, CHRONIC BRONCH, OTHER CHRONIC RESP DISEASES
RTECS: 9999999ZZ
FROM WORKING W/MDI. ONCE A PERSON IS DIAGNOSED AS
RTECS: 9999999ZZ
LOOSELY, & ALLOW TO STAND FOR 14-48 HRS. WASH
RTECS: 9999999ZZ
NON-IONIC SURFACTANT UNION CARBIDE'S TERGITOL TMN-10
RTECS: 9999999ZZ
(90-95%). RESPIRATORY PROTECTION IS RECOMMENDED
RTECS: 9999999ZZ
NEAR TLV, AN NIOSH/MSHA APPRVD AIR-PURIFYING RESP
RTECS: 9999999ZZ
CAN BE USED. HOWEVER, DUE TO POOR WARNING PROPERTIES
RTECS: 9999999ZZ
W/SKIN PROTEIN & TISSUE MOISTURE & CAN CAUSE
RTECS: 9999999ZZ
ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER;
CAS: 101-68-8
RTECS: NQ9350000
Fraction By Weight: 73%
OSHA PEL 0.02 PPM, C
ACGIH TLV: 0.005 PPM
EPA Report Quantity: 1 LB
DOT Report Quantity: 1 LB
COULD BE IMMED/DELAYED & INCL CHEST TIGHT, RESP
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:NONE NORMALLY REQUIRED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: INHAL OF MDI VAPS/AEROSOLS IN
CONC ABOVE 0.02PPM CAN PRDCE IRRIT OF MUC MEMB IN RESP TRACT,
RUNNING NOSE, SORE THROAT, PRODUCTIVE COUGH & A REDUCTION IN LUNG
FUNC. EXTENSIVE EXPOS TO CONC WELL ABOVE TLV COULD LEAD TO BRONCH,
BRONCHIAL SPASM & PULM EDEMA. THESE EFTS ARE USUALLY REVERSIBLE.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: HOWEVER, DUE TO LOW VOLATILITY, HIGH
EXPOS ARE NOT ANTICIPATED EXCEPT IF MATL IS OVERHEATED/SPRAYED AS
AN AEROSOL INTO AIR. HYPERSENSITIVITY PNEUM HAS ALSO BEEN RPTD.
ANOTHER TYPE OF RESPONS E IS HYPERREACTIVITY OR HYPERSENSITIZATION.
PERSON W/PREEXISTING UNSPEC ISOCYANATE HYPERSENSITIVITY (AS (SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:EYE: FLUSH W/CLEAN, LUKE WARM H*2O (LOW PRESS) FOR @ LST 15
MIN, OCCAS LIFT LIDS, & OBTAIN MED ATTN. SKIN: REMOVE CONTAMD
CLTHG. WASH AFFECTED AREAS THORO W/SOAP & H*2O. WASH CONTAMD CLTHG
THORO BEFOR E REUSE. INHAL: MOVE TO AN AREA FREE FROM RISK FURTHER
EXPOS. ADMIN O*2/ARTF RESP AS NEEDED. OBTAIN MED ATTN.
ASTHMATIC-TYPE SYMP MAY DEVELOP & MAY BE IMMED/DELAYED UP TO
SEVERAL HRS. TRTMT (ING 8)
Fire Fighting
Flash Point Method:PMCC
Flash Point:>350F,>177C
Extinguishing Media:DRY CHEM, (E.G. MONOAMMONIUM PHOSPHATE, POTASSIUM
SULFATE, & POTASSIUM CHLORIDE, CO*2, HIGH EXPANSION (SUPP DATA)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. USE
COOL WATER TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DURING A FIRE, MDI VAPS & OTHER
IRRITATING, HIGHLY TOX GASES MAY BE GENERATED BY THERMAL
DECOMP/COMBUSTION. @ TEMP >400F(204C), POLYMERIC MDI CAN (SUPP
DATA)
Accidental Release
Spill Release Procedures:COVER SPILL W/SAWDUST, VERMICULITE, FULLER'S
EARTH/OTHER ABSORB MATL. POUR DECONTAM SOLN OVER SPILL AREA & ALLOW
TO REACT FOR @ LST 10 MIN. COLLECT MATL IN OPEN CONTRS & ADD
FURTHER AMTS OF DECONTAM S OLN. REMOVE CONTRS TO A SAFE PLACE,
COVER (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:STORE IN TIGHTLY CLSD CONTRS TO
PREVENT MOISTURE CONTAMINATION. DO NOT RESEAL IF CONTAMINATION IS
SUSPECTED. AVOID CONTACT WITH SKIN AND EYES.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
Exposure Controls
Respiratory Protection:AN NIOSH/MSHA APPRVD AIR-SUPPLIED RESP MUST BE
WORN DURING SPRAY APPLICATN, DURING LONG-TERM (OVER 1HR) EXPOS WHEN
PROD IS HEATED/IN ENVIRON OF HIGH CONC WELL ABOVE TLV OF 0.02PPM.
FOR SHORT-TERM (<1H R) EMER SITUATIONS @ CONC (ING 15)
Ventilation:LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW TLV
WHENEVER MDI IS PROCESSED OR HEATED.
Protective Gloves:CHEM RESISTANT GLOVES (NATURAL (ING 18)
Eye Protection:CHEM WORK GOG & FULL LNGTH FSHLD.
Other Protective Equipment:SFTY SHOWERS & EYE WASH STATIONS SHOULD BE
AVAILABLE. EDUCATE & TRAIN EMPLOYEES IN SAFE USE OF PRODUCT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: (PROTEINIC) CHEM FOAM, WATER SPRAY FOR LG FIRES. EXPLO
HAZ: POLYMERIZE & DECOMPOSE WHICH CAN CAUSE PRESS BUILD-UP IN CLSD
CONTRS. EXPLO RUPTURE IS POSS. EFTS OF OVEREXP: A RSLT OF PERVIO US
RPTD OVEREXP/SINGLE LG DOSAGE) WILL RESPOND TO SM ISOCYANATE CONC @
LEVELS WELL BELOW TLV OF 0.02PPM. SYMP (ING 2)
Chemical Properties
HCC:T4
Spec Gravity:1.23@77F
Appearance and Odor:YELLOW LIQUID, WITH A SLIGHTLY MUSTY ODOR.
Percent Volatiles by Volume:NEGLIG
Stability
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS. WILL CAUSE SOME CORROSION TO
COPPER ALLOYS & ALUMINUM.
Stability Condition to Avoid:REACTS SLOWLY WITH WATER TO LIBERATE CO*2
GAS.
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CO, NO*X, TRACES
OF HCN, MDI.
Disposal
Waste Disposal Methods:WASTE MUST BE DISPOSED OF I/A/W FED, ST, & LOCAL
ENVIRON CTL REGS. INCIN IS PREFERRED METH. EMPTY CONTRS MUST BE
HNDLD W/CARE DUE TO PROD RESIDUE. DECONTAMINATE CONTAINERS PRIOR TO
DISPOSAL. DO NOT HE AT OR CUT EMPTY CONTR W/ELECTRIC/GAS TORCH.
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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.